In a right triangle
where a and b are the legs, and c is the hypotenuse, which is the longest side.
Check if 
25 + 64 = 89, which is not 81 (9 squared). This is not a right triangle.
Pyhtagorean Triples are sets of numbers, side lengths, that make up right triangles. If you memorize the first few Pythagorean Triples, problems like this are easy.