An isosceles triangle has at least two equal sides, and thus at least two equal angles. Since this triangle has a larger vertex angle, it is not equilateral. It has two equal base angles.
The sum of the interior angles of a triangle is 180.
Call each base angle x, call the vertex angle 3x.
x + x + 3x = 180
5x = 180
x = 36.
The base angles are each 36 degrees, and the vertex angle is 3*36 = 108 degrees.