From 0 to 100 points is 101 possible different scores.
If there were 101 students, it is possible, although
extremely unlikely, that each one could have a different
score. However if there were 102 students it would
be impossible for all students to have different
scores, for then there wouldn't be enough possible
scores for every student to have a different one.
So the answer is 102 or more students.
Edwin