If the time is 5 hours and x minutes after 5:00, then the angle formed by the minute hand is (x/60)(360) = 6x (degrees). For each minute after 5, the hour hand moves 1/2 degree, so the hour hand has an angle of 150 + x/2. The angle between them is 90 degrees, so
or
or
Therefore the angle between the hands is 90 at roughly 5:11 and 5:44.