4) Correct.
5) 
a)  With Replacement
                   # of red marbles      12
P(First is red) = ------------------ =  ----
                  total # of marbles     25
Since you are replacing the marble (ie putting it back), this means that the total number of marbles stays the same
                      # of black marbles      13
P(Second is black) = ------------------ =  -------
                     total # of marbles       25
-----------------------------------------------------------------------------
b) Without Replacement
                   # of red marbles      12
P(First is red) = ------------------ =  ----
                  total # of marbles     25
Now since you are NOT replacing the marble, this means that the total number of marbles will go from 25 to 24
                      # of black marbles            13         13
P(Second is black) = ----------------------    = --------- =  -----
                     total # of marbles - 1         25-1       24