Refer to the figure above, where we've sliced the original picture down the middle.  Here 
.   If we maximize this figure in terms of 
, we just need to double that to find 
.
 = 
 = 
Observe:
 
Substituting for r and h:
 = 
 = 
 = 
= 
 + 
...factoring out 
= 
   (*)
Now take the derivative of 
 with respect to 
:
 = 
   
= 
... substitute 
 ...
= 
  
This last function is zero at approx.  
 = 2.575rad, 
= 5.716rad, ...
By graphing, one can see 2.575rad  results in a maximum area, while 5.716 results in a minimal area.   
2.575rad is approx 147.54degrees.
Ans: 
 = 
 maximizes the total area.
Just in case...
If you were interested in the value of the total maximal area, note that you would need a modified form of (*) because that equation computes 1/2 of the total area:
 
 =