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For each mass, calculate the corresponding shear force, directed along the incline; then compare them.
For the left mass, the shear force is 100*sin(30°) =
= 50.0 pounds.
For the right mass, the shear force is 85*sin(45°) =
= 60.10 pounds.
For the right mass, the shear force is greater; hence, WHAT ?
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On incline planes, you may learn the subject and the terminology from this Wikipedia article
https://en.wikipedia.org/wiki/Inclined_plane
or from many other good sources in the Internet. The key word is "incline plane" in GOOGLE searching machine.