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First question
31 = 2 + 29. This and only this number.
HINT. One of the two addends must be 2, the only even prime number.
Second question
35 = 3 + 13 + 19 (the sum of three odd prime numbers)
31 = 3 + 11 + 17 (the sum of three odd prime numbers)
65 = 3 + 19 + 43 (the sum of three odd prime numbers)
Solved.