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f(x) = x^2 - bx + 9.
f(x) has one rational root if and only if the discriminant of this quadratic equation is zero
d = (-b)^2 - 4*1*9 = 0, or b^2 - 36 = 0,
which implies b = +/-6.
Since the problem requires b > 0, there is only one solution b = 6.