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The denominator has two terms. To rationalize this denominator we need to find a way to take a two-term expression and change it into an expression of nothing but perfect squares. Since multiplying the numerator and denominator is the primary way to change a denominator, we are looking for an expression we can multiply your denominator by to get an expression of perfect squares.
The key to this is the pattern:
On the left we have two two-term expressions being multiplied. And on the right we have an expression of perfect squares! This can be used to rationalize any two-term denominator with 1 or 2 square roots.
Your two-term denominator has a "+" between the two terms. So your denominator is the (a+b). We need to multiply by (a-b):
Not only did we rationalize the denominator, we eliminated the fraction entirely!