This is a conditional probability problem:
Sample space =
{GG, GB, BG, BB} where the first letter, G or B, represents the
older and the second letter represents the younger.
Since we are given that at least one of the children is a girl, the
reduced sample space does not include BB.
Reduced sample space =
{GG, GB, BG}
The only successful ones are GG and BG.
That's 2 ways out of 3.
So the conditional probability is 2/3
Edwin