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There are 12 picture cards, 4 Jacks, 4 Queens, and 4 Kings.
So there are "12 choose 5" ways to choose 5 picture cards.
There are 52 cards in the deck.
So there are "52 choose 5" ways to choose any 5 cards.
So the desired probability is 12C5 ways out of 52C5 or
12C5 792 33
---- = --------- = -------- = 0.0003047372795
52C5 2598960 108290
Edwin