nCk is the number of Combinations of n items taken k at a time.
= .
nPk is the number of Permutations of k items taken from the set of n elements
= n*(n-1)*(n-2)* . . . * (n-k+1).
We consider combinations when we select the groups of k items from the set of n items without looking on their order (when the order does not matter).
We consider permutations when we select the groups of k items from the set of n items and consider these groups as ordered sets (when the order does matter).
Again, or one more time:
nCk is the number of all subsets of k elements of a given set of n elements.
nPk is the number of all ordered subsets of k elements of a given set of n elements.