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The critical points, for finite x, are at x=0 and x=1/2.
f(0) = 0 (local minimum)
f(1/2) = 0.001144727 (local maximum)
Note that f(x) is always nonnegative (x^4 is nonnegative and e^(-8x) is always positive so the product is always nonnegative).
Here is a close up of f(x) and f'(x), zoomed way in, red graph is f'(x):