.
If the segments are the sides of a quadrilateral then the quadrilateral is EITHER a kite OR a rhombus.
In both case its diagonals are perpendicular.
So the statement is true.
On properties of rhombis, see the lessons
- Diagonals of a rhombus are perpendicular
- Diagonals of a rhombus bisect its angles
in this site.
Also, you have this free of charge online textbook on Geometry
GEOMETRY - YOUR ONLINE TEXTBOOK
in this site.
The referred lessons are the part if this textbook under the topic "Properties of rhombis".