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Let me to educate you a bit (a little).
The equality ad = bc means that the determinant of the matrix is equal to zero. (*)
This equality also means that the vectors (a,b) and (c,d) are proportional. (**)
These (*) and (**) are EQUIVALENT properties.
Having this HINT will help you easily answer your questions.
a) Regarding "reflexivity" property
The property (the term) "reflexive" means that element E satisfies the relation ErE.
ANY element of your list satisfies this property.
By the way, to check whether this property is valid, you DO NOT NEED to treat two different elements of your set.
The reflexive property must be checked for EACH element individually, not for the pair of elements.
In this sense the formulation a) in your post IS INCORRECT.
b) Regarding "symmetric" property
The example of two elements that demonstrate the symmetric property is
(1,2) and (2,4).
You may check it immediately, making the necessary calculations manually.
c) Regarding "transitivity" property.
The property (**) makes transitivity OBVIOUS in this case:
If vector A is proportional to vector B, And B is proportional to C, then CLEARLY A is proportional to C
and the transitivity is on the place.
d) Regarding classes of equivalency.
The element (1,2) has equivalent (2,4), (3,6). (1)
The element (1,4) has equivalent (2,8), (3,12). (2)
The element (1,3) has equivalent (2,6). (3)
The element (3,4) is equivalent to itself and to nothing else. (4)
So, the lists (1), (2), (3) and (4) represent four classes of equivalency.
Solved.