Think of handcuffing the two together that mist sit next to each other and then you only have 4 "things" to seat, 3 single people and 1 couple handcuffed together. There are 2 ways to handcuff them together. For each of the two ways to handcuff them together, there are 4! ways to seat the four "things", so the answer is 2*4! = 2*4*3*2*1 = 48 ways. Edwin