.
This problem is posed incorrectly and is SELF-CONTRADICTING.
If to understand it precisely as it is written, then the set of all possible solutions is in this table below
n First Second The The The
number number sum difference pairs
---------------------------------------------------------
1 23 22 45 1 (23,22)
2 24 21 45 3 (24,21)
3 25 20 45 5 (25,20)
4 26 19 45 7 (26,19)
5 27 18 45 9 (27,18)
6 22 23 45 -1 (22,23)
7 21 24 45 -3 (21,24)
8 20 25 45 -5 (20,25)
9 19 26 45 -7 (19,26)
10 18 27 45 -9 (18,27)
11 17 28 45 -11 (17,28)
12 16 29 45 -13 (16,29)
13 15 30 45 -15 (15,30)
14 14 31 45 -17 (14,31)
15 13 32 45 -19 (13,32)
16 12 33 45 -21 (12,33)
17 11 34 45 -23 (11,34)
18 10 35 45 -25 (10,35)
19 9 36 45 -27 ( 9,36)
20 8 37 45 -29 ( 8,37)
21 7 38 45 -31 ( 7,38)
22 6 39 45 -33 ( 6,39)
23 5 40 45 -35 ( 5,40)
24 4 41 45 -37 ( 4,41)
25 3 42 45 -39 ( 3,42)
26 2 43 45 -41 ( 2,43)
27 1 44 45 -43 ( 1,44)
As you see, there are 27 solutions, which number 27 is not in your list of possible answers.
All 27 pairs in the last column are different and satisfy the problem's requirement.
Therefore, the conclusion is: the problem formulation is FATALLY and TOTALLY wrong.
I clearly understand that this problem, as presented in this post, migrates in the Internet
from site to site during the years, while its right place is in GARBAGE BIN.
I saw this problem (or similar, or in similar formulations) at this forum years ago,
and saw discussions of it by different tutors.
My point of view is that such GIBBERISH does not deserve any discussion.
What it really deserves, is to be removed/deleted from the Internet.